10.626 Lecture Notes, Electrostatic Correlations
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چکیده
Until now, we have developed continuum models for the dynamics of electrolytes at the macroscopic scale, much larger than typical length scales for intermolecular forces. In particular, we have used principles of nonequlibrium thermodynamics, to arrive at general models of interfacial voltage (Nernst equation), reaction kinetics (Butler-Volmer equation), and transport (Poisson-Nernst-Planck equations):
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